Remove contact lenses, if worn, while flushing. Current Edition: 2022 View Document Scope NFPA, GHS, & SDS Revised 4/11/14 NFPA FIRE DIAMONDS & GHS SYMBOLS SAFETY DATA SHEETS (SDS) The NFPA (National Fire Protection Association) 704 or NFPA Diamond is the standard for the identification of hazardous materials and emergency response. Hazardous Polymerization: Will not occur. These labels can withstand the abuse of an industrial workplace. Calculators & Tools. . For stored carbon dioxide gas, the "health" rating is 3 out of a 0-4 scale. When calcium chloride is added to hot water it causes violent boiling. Calcium Sulfate, Dihydrate Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com CAS 10101-41-4 Calcium Sulfate, Dihydrate >95 % Percentages are by weight SECTION 4 : First aid measures Description of first aid measures After inhalation: Remove to fresh air. immediately or shortly after exposure to Copper Chloride: * Contact can severely irritate and burn the skin and eyes with possible eye damage. Long term exposure of calcium chloride solution upon a zinc coated galvanized iron vessel caused slow evolution of hydrogen which ignited and exploded [Bretherick, 5th Ed., 1995]. Hazardous Decomposition Products: Hydrogen chloride, sodium oxide. It can be created by neutralising hydrochloric acid with calcium . 15.2. International regulations . . NFPA Reactivity Catagory. Aluminum hydroxide or oxide is slowly solubilized in the stomach and reacts with hydrochloric acid to form aluminum chloride and water.In addition to forming aluminum chloride, dihydroxyaluminum sodium carbonate and aluminum carbonate form carbon dioxide, and aluminum phosphate forms phosphoric acid.About 17-30% of the aluminum chloride formed is absorbed and is rapidly excreted by the kidneys . Hazardous Decomposition Products: Hydrogen chloride, oxides of iron Hazardous Polymerization: Will not occur Section 11 : Toxicological Information Routes of Entry: Eye contact. This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR 372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Little Pro on 2015-12-30 . NFPA SUPPLIER Santa Cruz Biotechnology, Inc. 2145 Delaware Avenue Santa Cruz, California 95060 800.457.3801 or 831.457.3800 EMERGENCY : 7647-14-5 Product code : LC23420 Formula : NaCl 1.2. The four divisions of the sign are typically color-coded with: Each of the "flammability," "health," and . NFPA 704 Hazard Diamond Explanation Guide The National Fire Protection Agency (NFPA), in section 704 of the National Fire Code, specifies a system for identifying hazards associated with various materials. Reactivity Alerts Known Catalytic Activity Water-Reactive Air-Reactive Air & Water Reactions Fumes in moist air (forms a large amount of hydrogen chloride gas). Liquid Helium, Ammonium Fluoride, Ammonium Sulfate, Arsenic Chloride, Calcium Cyanide, Carbon Tetrachloride, Chlorine, Hydrobromic Acid, Hydrochloric Acid, Mercuric Cyanide, Nitric Acid, Nitrogen (liquified), Nitrogen Peroxide, Nitrogen Trioxide . CAS 10043-52-4 Calcium Chloride,Anh,ACS,2.5KG 100 % Percentages are by weight SECTION 4 : First aid measures Description of first aid measures After inhalation: Move exposed person to fresh air; if breathing is difficult, give oxygen. Density (at 25C): 2.2 g/cm. Hazard Ratings for NFPA Diamonds This appendix provides hazard-rating information for many chemicals that might be found in a laboratory. Lethal dose or concentration (LD, LC): LD 50 (median dose) . This Danger: Calcium Chloride Landscape With Icon - Wall Sign is constructed using durable, industrial-grade materials, and is designed to be easily noticeable from a distance. Calcium hydroxide Minnesota: Calcium hydroxide Massachusetts RTK: Calcium hydroxide New Jersey: Calcium hydroxide California Director's list of Hazardous Substances: Calcium . Section 11 - Toxicological Information RTECS#: CAS# 7647-14-5: VZ4725000 LD50/LC50: CAS# 7647-14-5: . Hazards What is this information? Section . Diamond Hazard Value Description; 0 3 2 W: Health 3: Can cause serious or permanent injury. NFPA 704. Avoid generating dusty conditions. Product Name Calcium chloride, 1M aq. [1] This compound is relatively stable and has greater available chlorine than sodium hypochlorite. EMERGENCY TELEPHONE: 281-561-1600 SUPPLIER: Supplied by a Business Unit of M-I L.L.C. SEE GLOSSARY ON PAGE 5. calcium chloride Calcium chloride hexahydrate 24 mg/m3 260 mg/m3 1,600 mg/m3 (USCG, 1999) Silver nitrate; sodium chlorate; 25% ammonium hydroxide; produces shock-sensitive dark crystals. Recommended use and restrictions on use Use of the substance/mixture : For laboratory and manufacturing use only. Ingesting calcium chloride is a serious safety and health risk. Fire Extinguisher Calcultor; . f This chemical is on the Special Health Hazard Substance List. SAFETY DATA SHEET: CALCIUM SULFATE, Anhydrous CALCIUM SULFATE, Anhydrous C162.10; C162.32; D925.50; D935.50 INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887) 1216 6th Ave N Kent WA 98032 Phone: 253-479-7000 CaSO4 136.14 Recommended Use: Restrictions on Use: Commercial/industrial use Product Name: no. . Calcium chloride is an inorganic compound, a salt with the chemical formula CaCl 2. - Calcium chloride. Used to make acetylene and in steel manufacture. Weighting agent. Toxicity to Animals: This compound absorbs moisture intensively and is known as desalting substances. . Ammonia is a colorless gas, with a pungent odor. CALCIUM CHLORIDE Labels Product Highlights Dimensions: 3.75 in H x 4.5 in W Color: Black on Yellow Material Number: B-928 (View Technical Data Sheet) Label Properties: Aggressive Adhesive, Permanent Adhesive Add To Compare $45.19 (USD) / pack of 25 labels Part Number: 93501 Add To Cart Add To Favorites (NFPA, 2010) General Description Grayish-black irregular lump solid. Blue = (en) Calcium dichloride E509. This can lead to vomiting, extreme thirst, stomach pain, and low blood pressure. Inhalation causes irritation of nose and throat. Reactivity Alerts Strong Reducing Agent Water-Reactive Pyrophoric Air & Water Reactions Pyrophoric ignites in air when finely divided, then burns with crimson flame [Merck 11th ed. Saturated Sodium Chloride 04. * Breathing Copper Chloride can irritate the nose, throat and lungs causing coughing and wheezing. Calcium chloride, ACS - 1 - Section 1 - Chemical Product and Company Identification MSDS Name: Calcium chloride, ACS Catalog Numbers: LC12725 Synonyms: Calcium dichloride dihydrate. Seek immediate medical attention After skin . Do not let this chemical enter the environment. Made from our durable high quality vinyl that is designed to survive harsh environments and provide years of service. Accidental release measures Personal Precautions Ensure adequate ventilation . A strong irritant to skin, eyes and mucous membranes. You will be using 6M HCl and 6 M NaOH in this week's lab. sodium chloride code H 1: Health code 1: Exposure would cause irritation but only minor residual injury. Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of: Platinum chloro-tetrazole complexes via azidation. Loosen clothing and place exposed individual in a comfortable position. Wash off immediately with plenty of water for at least 15 minutes. 200mL Water Sample #4 (0.1M Calcium Chloride) 200mL Water Sample #5 (0.05M Calcium Chloride) 200mL Water Sample #6 (0.9M Calcium Chloride) Materials needed but not supplied: 250mL Beakers 100mL Beakers 100mL Graduated Cylinders Watch Glasses Distilled or Deionized Water Wash Bottles Analytical This degree should include any material which will not burn in air when exposed to a temperature of 1500F (815.5C) for a period of 5 minutes. Calcium chloride without water contents (anhydrous) has 110.98 g/mol molecular mass. Strong oxidizing agents, alkali metals, allyl chloride, ethylene oxide, potassium, sodium. Reactivity Alerts Water-Reactive Air & Water Reactions Crumbles on exposure to moist air. 1989]. E.g. Obtain medical attention. Company Identification: LabChem, Inc. 200 William Pitt Way Pittsburgh, PA 15238 Company Phone Number: (412) 826-5230 Emergency Phone Number: (800) 424-9300 CHEMTREC . Firefighting measures (NFPA, 2010) General Description A white to gray powder with a pungent odor. Contact with eyes (particularly by dust) causes irritation and possible transient corneal injury. traceable to SRM from NIST Ca (NO) in HNO 0.5 mol/l 1000 mg/l Ca Certipur Calcium standard solution MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Melting point: 772C. Barium chloride accumulates in plants when it exceeds calcium and magnesium levels in soil. This means "Short exposure could cause serious temporary or moderate residual . DAIMON SHIP SUPPLIMENT > Uncategorized > strontium chloride nfpa > Uncategorized > strontium chloride nfpa Uses advised against Food, drug, pesticide or biocidal product use. NFPA 704 rating system is a standard system developed by the U.S.-based National Fire Protection Association (NFPA) for indicating the health, flammability, reactivity and special hazards for many hazardous chemicals through the use of the NFPA 704 Diamond. Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Cobalt(II) chloride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. Inhalation. Page 1 of 6 MSDS - Calcium Carbonate Material Safety Data Sheet (MSDS) - Calcium carbonate 1. Pentiptycenes for use as light-driven molecular brakes. Use this reference to complete the health, fire, reactivity, and special notice (S-N) areas in the diamond. The NFPA 704 Diamond, commonly referred to as the NFPA Hazard Diamond, provides a system for identifying the specific hazards of a material and the severity of the hazard that would occur during an emergency response. Sodium Chloride CAS # 7647-14-5 Solubility In Water 35.7g/100g at 0C 1.233mt/m3 (77lb/ft3) Odour and Appearance Odour Threshold Not Available Flammability Non Flammable Means of Extinction Non Combustible NFPA Classification MATERIAL SAFETY DATA SHEET Boiling Point 1465C Specific Gravity SECTION III - PHYSICAL DATA SODIUM CHLORIDE SECTION IV - FIRE AND EXPLOSION HAZARDS SECTION I . It is designed to be used in a table. 1:164, 165 1956]. NFPA 704 Sign with Ratings 3,0,0 - NFPA-0007 - from MySafetySign.com (800) 952-1457; Free . (NFPA, 2010) General Description An odorless, white or gray-white solid in the form of hard lumps. Use personal protective equipment. Hazards What is this information? Hazards What is this information? Exposure to ammonia in small amounts can cause irritation to the eyes, nose and throat. Chemical Product and Company Identification Product Name : Calcium carbonate Catalog Codes : SLC1141, SLC4720, SLC4438, SLC1645 CAS# : 471 -34 -1 RTECS : FF9335000 TSCA : TSCA 8(b) inventory: Calcium carbonate These signs can be found on reagent bottles, gas tanks, vehicles that transport chemicals, and doors . NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this SDSs are NOT to be used to fill in the NFPA 704 diamond. First aid measures Description of first aid measures: Inhalation: Remove to fresh air. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. Formula: CaCl 2. Supplier LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's . The vapor-phase co-reductions with other metal halides such as aluminum chloride (cat. NFPA 704 (NFPA, 2010) General Description A silvery, soft metal that turns grayish white on exposure to air. Details of the supplier of the safety data sheet Emergency Telephone Number During normal business hours (Monday-Friday, 8am-7pm EST), call (800) 343-0660. Abundance in the Universe. Oil well completion fluid additive. NFPA 704 (fire diamond) [9] 2 . NFPA, DOT and OSHA Placard and Pictograms 3. : J63122 Synonyms No information available Recommended Use Laboratory chemicals. Ingestion causes irritation of mouth and stomach. If breathing is . Provide ventilation. Each of the 4 quadrants on a NFPA 704 diamond have a color with a number or symbol inside it. Durable laminate that increases the label strength and resistance. Electron Affinity. A straw-colored liquid. soln. Solubility in water: 0.185 g/100 ml @ 0 deg. NFPA SCALE (0-4) HMIS RATINGS (0-4) . +65 6225 6286 www.chemtradeasia.com 2 This template produces a NFPA 704 fire diamond with optionally four hazard codes. If not breathing, give artificial respiration. calcium code R 2: Reactivity code 2: Undergoes violent chemical change at elevated temperatures and . SDS CoA Brochures Certificates 119778 View Pricing & Availability Download Product Safety Card Recommended Products Overview calcium ascorbate: calcium carbonate: calcium chloride 38%: calcium chloride flake: calcium chloride pellets: calcium chloride powder: caprolactam: capric acid 99%: caprylic acid 99%: castor oil: caustic soda 25% : caustic soda 50% diaphragm: caustic soda 50% membrane: caustic soda 50% rayon: caustic soda beads: caustic soda flake: celpure s300 . C; 0.077 g/100 ml @ 100 deg. Carbon monoxide (CO) Carbon dioxide (CO2) Calcium oxides Sulfur oxides Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Instability 2: Readily undergoes violent chemical changes at elevated temperatures and pressures. Denser than water . This standard presents a simple, readily recognized, and easily understood system of markings (commonly referred to as the "NFPA hazard diamond") that provides an immediate general sense of the hazards of a material and the severity of these hazards as they relate to emergency response. NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0 . ), > 97%, (CAS# 10361-37-2) which is subject to the reporting . Trans-stilbenes and cinnamates via Wittig olefination. Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use 1.3. Molecular mass: 111.0. NFPA 704 labels are required when another Federal, state or local regulation or code requires their use. E.g. Ingestion. This Danger: Calcium Chloride - Label can be placed on products, packaging, equipment, and other locations where larger signage might not be a good fit. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. It can cause burns to the mouth, throat, and stomach. Special W Reacts violently or explosively with water. The quadrants are arranged as follows: In each quadrant is a rating assigned by an expert. Skin Contact At higher levels, ammonia may turn fatal due to throat swelling or chemical . FIRST AID Eye Contact f Workplace Exposure Limits Immediately flush with large amounts of water for at least 15 minutes, lifting upper and lower lids. NFPA. 146 Molecular Formula: C 20 H 24 CaO 10 S 2 Molecular Weight: 528.60656 Main Specification calcium lignosulfonate grade One calcium lignosulfonate grade two calcium lignosulfonate grade three Uses +65 6227 6365 - Fax. Electronegativity. >. Calcium hypochlorite is an inorganic compound with formula Ca(OCl) 2.It is the main active ingredient of commercial products called bleaching powder, chlorine powder, or chlorinated lime, used for water treatment and as a bleaching agent. Corrosive to tissue and toxic by ingestion. Calcium Chloride Chemwatch: 5210-59 Version No: 3.1.1.1 Safety Data Sheet according to OSHA HazCom Standard (2012) requirements . This presents another risk of burn injuries. This compound is relatively stable and has greater available chlorine than sodium hypochlorite. Mix potassium chlorate with antimony sulfate, wet, in 5% gum arabic solution; some preparations add sulfur and ground glass, sometimes also calcium carbonate and/or meal powder. It is widely used as a refrigerant and for the manufacture of products such as pesticides, fertilizer, plastic and other chemicals. Skin Contact: Wash with soap and plenty of water. Record the NFPA diamond for this solution in your lab notebook. 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